Accurate measurement of external quantum efficiency(EQE) of cells embedded in PV modules is critical for reducing the uncertainty of the flash I-V measurements during secondary calibration of PV mod. ••Robustness of a non-destructive method for measuring EQE of cells. The External Quantum efficiency of cells embedded in PV modules is an important measurement required for minimizing the uncertainty in the module power measurements e. A PSpice model was developed for a commercial module to understand the impact of different parameters of the cells in the module while measuring the EQE of the target cell (Casta. A PSpice model was developed for a 60-cell module with 3 bypass diodes. This model was used to illustrate the effect of various sources of errors in the non-destructive EQE. The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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What causes errors in cell-to-cell electrical properties?
This paper presents detailed analysis and quantification of possible sources of errors due to various factors such as shading of target cell, load point determination, variance in cell-to-cell electrical properties and use of AC probe light.
Can quantum efficiency be used for solar cell loss analysis?
We suggest a new solar cell loss analysis using the external quantum efficiency (EQE) measured with sufficiently high sensitivity to also account for defects.
Are sub-band-gap states a new metric for solar cell loss analysis?
To conclude, with the use of recent advancements in understanding the thermodynamic limits of solar cells, namely, the implementation of band-filling, we attempted to include sub-band-gap states to define a new metric, VOC,EQE, that allows for more advanced and accurate loss analysis of solar cells.
What causes optical losses in solar PV?
In conclusion, optical losses can be caused by many of the common defects in solar PV, making them a potentially useful source of losses to monitor and analyze when it comes to PV defects in general. 1.2. Quantum efficiency fundamentals
What is the ideality factor of c-Si PERC and CIGS solar cells?
The parameter “diode ideality factor” (n) in the model controls these characteristics. The c-Si PERC and CIGS cells used in this analysis have ideality factors of 1.1 and 1.58, respectively. We altered the ideality factor of the CIGS solar cell while maintaining its nominal power.
Can EQE be measured under a solar cell without a UV pattern?
With aims to further confirm this fact, an experiment was performed where the EQE of a selected solar cell is measured at a spot where the pattern exists, and compared to an EQE measurement of the same cell under an area without the UV pattern.